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Search Results for " histone h3 "

46

抑制剂 & 化合物

1

天然产物

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Cat. No.	Product Name	Target	Signaling Pathways
T38766L	Histone H3 (1-35) acetate	Others	Others
	Histone H3 (1-35) acetate 是组蛋白 H3 的 35 个残基肽。组蛋白 H3 是一种重要的蛋白质，在基因的动态和长期调控中发挥作用。
T38766	Histone H3 (1-35) Histone H3 (1-35)
	Histone H3 (1-35) is a 35-residue peptide derived from histone H3, which is a key member of the five main histones participating in the formation of chromatin within eukaryotic cells.
T38785	Histone H3 (21-44) Histone H3 (21-44)
	Histone H3 (21-44), derived from a sequence of 21-44 amino acids of histone H3, is commonly employed as a substrate, particularly for protein arginine methyltransferase assays, where methylation activity is being examined.
T40993	Histone H3 (1-21) Histone H3 (1-21)
	Histone H3 (1-21) is a truncated form of the Histone H3 protein consisting of amino acids 1 to 21. It serves as a common substrate for methyltransferase assays targeting Histone 3 at lysine 4 and lysine 9, as well as for acetyltransferase assays targeting Histone 3 at lysine 9 and lysine 14.
T39580	Histone H3 (23-34) Histone H3 (23-34)
	Histone H3 (23-34) is a peptide consisting of amino acid residues 23 to 34 of the histone H3 protein. This peptide specifically includes lysine residues at positions 23 and 27, which can undergo methylation and acetylation modifications.
T40407	Histone H3 (5-23) Histone H3 (5-23)
	Histone H3 (5-23), a derivative of histone H3 consisting of amino acids 5-23, serves as a substrate for histone acetyltransferase (HAT) assays.
T38784	Histone H3 (1-25), amide Histone H3 (1-25), amide
	Histone H3 (1-25), amide is a N-terminal peptide fragment of histone H3 that serves as a substrate for histone methyltransferases (HMTs). It can be utilized to identify the substrate for HMTs. Compared to histone H3 (15-39) and full-length histone H3, Histone H3 (1-25), amide proves to be more efficient as a substrate for HMT G9a.
T41061	Histone H3 (116-136), C116-136 Histone H3 (116-136), C116-136
	Histone H3 (116-136), C116-136 is a peptide consisting of amino acids 116 to 136, which spans the C-terminus of histone H3.
T36576	Histone H3 (21-44)-GK-biotin (trifluoroacetate salt) Histone H3 (21-44)-GK-biotin (trifluoroacetate salt)
	Histone H3 (21-44)-GK-biotin is a peptide fragment of histone H3 that corresponds to amino acid residues 22-45 of the human histone H3.1 and 3.2 sequences and is biotinylated via a C-terminal GK linker. Histone H3 (21-44) contains a lysine residue at position 23 that is subject to acetylation, an arginine at position 26 subject to methylation, and a serine at position 28 subject to phosphorylation, as well as lysine residues at positions 27 and 36 that are subject to methylation and acetylation....
T36979	Histone H3 (21-44)-GK-biotin amide (trifluoroacetate salt) Histone H3 (21-44)-GK-biotin amide (trifluoroacetate salt)
	Histone H3 (21-44)-GK-biotin is a peptide fragment of histone H3 that corresponds to amino acid residues 22-45 of the human histone H3.3 sequence and is biotinylated via a C-terminal GK linker. Unlike histone H3.1 and H3.2, the histone H3.3 variant contains a serine residue at position 31 that is phosphorylated during late prometaphase and metaphase of mitosis. Histone H3 (21-44) also contains lysine residues at positions 23, 27, and 36 that are subject to methylation and acetylation, all of whi...
T6421	BRD73954	HDAC	Chromatin/Epigenetic; DNA Damage/DNA Repair
	BRD73954 是一种有效且特异性的 HDAC 抑制剂，对 HDAC6 和 HDAC8 的 IC50 分别为 36 nM 和 120 nM。
TQ0059	Ilorasertib ABT-348	VEGFR; FLT; c-RET; PDGFR; Aurora Kinase	Angiogenesis; Apoptosis; Cell Cycle/Checkpoint; Chromatin/Epigenetic; Tyrosine Kinase/Adaptors
	Ilorasertib (ABT-348) 是一种 ATP 竞争性多靶点激酶抑制剂，可抑制 Aurora A、Aurora B 和Aurora C，IC50值为120 nM、7 nM 和1 nM。它还抑制 RET 酪氨酸激酶、PDGFRβ 和 Flt1，IC50为7 nM、3 nM 和 32 nM。
T64592	Histone H3 Antibody #9715R
	Histone H3 Antibody #9715R 是一种有用的有机化合物，可用于生命科学领域的相关研究，其产品编号为 T64592。
T0029	Procaine Duracaine,Spinocaine,普鲁卡因,Novocaine,Vitamin H3,奴夫卡因	Histone Demethylase; DNA/RNA Synthesis; Sodium Channel	Cell Cycle/Checkpoint; Chromatin/Epigenetic; DNA Damage/DNA Repair; Membrane transporter/Ion channel
	Procaine (Vitamin H3) 是DNA 脱甲基剂，是一种酯类局部麻醉剂。它起效缓慢，作用持续时间短，主要用于浸润麻醉、周围神经阻滞和脊髓阻滞。
T64611	Acetyl-Histone H3 (Lys9) (C5B11) Rabbit mAb #9649R
	Acetyl-Histone H3 (Lys9) (C5B11) Rabbit mAb #9649R 是一种有用的有机化合物，可用于生命科学领域的相关研究，其产品编号为 T64611。
T27083	Crebinostat	Epigenetic Reader Domain; Histone Acetyltransferase; HDAC	Chromatin/Epigenetic; DNA Damage/DNA Repair
	Crebinostat 是一种有效的组蛋白去乙酰化酶 (HDAC) 抑制剂，对 HDAC1、HDAC2、HDAC3 和 HDAC6 有抑制作用， IC50 分别为 0.7 nM、1.0 nM、2.0 nM 和 9.3 nM。Crebinostat 可增加在体外神经元的突触蛋白 1 斑点沿树突 (synapsin-1 punctae along dendrites) 的密度。Crebinostat 可调节染色质介导的神经可塑性，增强小鼠的记忆。Crebinostat 可诱导组蛋白 H3 和组蛋白 H4 乙酰化，并增强 cAMP 反应元件结合蛋白 (CREB) 靶基因 Egr1 的表达。
T5468	YF-2	Others; Epigenetic Reader Domain; Histone Acetyltransferase	Chromatin/Epigenetic; Others
	YF-2 是一种高选择性，可透过血脑屏障的组蛋白乙酰转移酶激动剂，能够在海马区乙酰化 H3，对 CBP、PCAF 和 GCN5 的EC50值分别为 2.75、29.04 和 49.31 μM，具有抗肿瘤和抗阿尔滋海默症的活性。
T8344	CPTH2	Apoptosis; Histone Acetyltransferase	Apoptosis; Chromatin/Epigenetic
	CPTH2 是一种组蛋白乙酰基转移酶抑制剂。它选择性地抑制Gcn5对组蛋白 H3 的乙酰化，通过抑制乙酰转移酶p300 (KAT3B)诱导凋亡并降低透明细胞肾癌细胞系的侵袭性。
T28996	TP-064 TP 064	Histone Methyltransferase	Chromatin/Epigenetic
	TP-064 是选择性蛋白精氨酸甲基转移酶 4 抑制剂，IC50小于10 nM，具有抗癌活性。它抑制 BAF155 和 MED12 的二甲基化，IC50为 340 和 43 nM。它对于 PRMT6 的 IC50为 1.3 μM。
T64529	MDL-800 MDL 800,MDL800	Sirtuin	Chromatin/Epigenetic; DNA Damage/DNA Repair
	SIRT6, responsible for deacetylation of histone H3 Nε-acetyl-lysines 9 (H3K9ac) and 56 (H3K56ac), is a tumor suppressor which has frequently been found to have low expression in various cancers. MDL-800 is a selective SIRT6 activator. It increased the deacetylase activity of SIRT6 by up to 22-fold and led to a global decrease in H3K9ac and H3K56ac levels in human hepatocellular carcinoma (HCC) cells. Also, it inhibited the proliferation of HCC cells via SIRT6-driven cell-cycle arrest and was eff...
T14936	Ivaltinostat CG-200745	HDAC	Chromatin/Epigenetic; DNA Damage/DNA Repair
	CG-200745 is a potent inhibitor of HDAC. CG200745 induces apoptosis and also inhibits the deacetylation of histone H3 and tubulin.
T29014	Tripartin
	Tripartin specifically inhibits the histone H3 lysine 9 demethylase KDM4 in HeLa cells.
T14839	Butyrolactone 3	Others	Others
	Butyrolactone 3 is a specifical inhibitor of the histone acetyltransferase Gcn5 (IC50: 100 μM) with a high affinity to the Gcn5 enzyme comparable to that of its natural substrate, histone H3. Butyrolactone 3 shows weak inhibitory on CBP (IC50: 0.5 mM).
T38774	E67-2 E67-2
	E67-2, a derivative of E67, is a low-toxicity, selective inhibitor of the KIAA1718 Jumonji domain. It has an IC 50 value of 3.4 μM. E67-2 specifically inhibits the Jumonji demethylase for histone H3 lysine 9 (H3K9) and histone H3 lysine 4 (H3K4) demethylase.
T36980	Histone H3K27Me1 (23-34) (trifluoroacetate salt) Histone H3K27Me1 (23-34) (trifluoroacetate salt)
	Histone H3K27Me1 (23-34) is a peptide fragment of histone H3 that corresponds to amino acid residues 24-35 of the human histone H3.1 and H3.2 sequences. Monomethylation of histone H3 at lysine 27 is associated with actively transcribed genes and positively correlates with H3K36 trimethylation. Levels of H3K27Me1 are increased in tumor tissue isolated from patients with metastatic hormone-na ve and castration-resistant prostate cancer. Histone H3K27Me1 (23-34) has been used in epitope mapping of ...
T11880	LSD1-IN-5	Histone Demethylase	Chromatin/Epigenetic
	LSD1-IN-5 increases dimethylated Lys4 of histone H3, shows no effect on expression of LSD1. LSD1-IN-5 is a potent and reversible inhibitor of lysine-specific demethylase 1 (LSD1), with an IC50 of 121 nM.
T11881	LSD1-IN-6	Histone Demethylase	Chromatin/Epigenetic
	LSD1-IN-6 increases dimethylated Lys4 of histone H3, shows no effect on expression of LSD1. LSD1-IN-6 is a potent and reversible inhibitor of lysine-specific demethylase 1 (LSD1), with an IC50 of 123 nM.
T39073	Amredobresib
	Amredobresib is a potent BET inhibitor that impedes the interaction between bromodomains and acetylated lysines on histone H3 and H4, thereby serving as crucial regulators of gene transcription. It proves valuable in the investigation of acute myeloid leukemia (AML) and cancer.
T81831	MDL-811	Sirtuin	Chromatin/Epigenetic; DNA Damage/DNA Repair
	MDL-811为SIRT6的异构激活剂，有效促进SIRT6对组蛋白H3的去乙酰化作用（H3K9Ac, H3K18Ac, 和 H3K56Ac）。该化合物在结肠癌研究中有应用价值。
T35817	Photoswitchable PAD Inhibitor (technical grade)
	Photoswitchable PAD inhibitor is a photoactivated protein arginine deiminase (PAD) inhibitor and a derivative of BB-Cl-amidine that contains an azobenzene photoswitch allowing optical control of PAD activity.1 Without photoactivation, it is a weak inhibitor of PAD2 (IC50 = >100 μM) and is less potent than BB-Cl-amidine in inhibiting citrulline production in vitro (kinact/KIs = 2,300, 600, 1,000, and 10,510 M-1min-1 for PAD1-4, respectively) and does not inhibit histone H3 citrullination in HEK29...
T82313	GK718	HDAC	Chromatin/Epigenetic; DNA Damage/DNA Repair
	GK718为一HDAC1/3特异性抑制剂，IC50值分别为259 nM和139 nM。该化合物能提升细胞内乙酰化组蛋白H3含量，并能够抑制Bleomycin所诱导的小鼠肺纤维化现象。
T83755	ssK36 TFA
	ssK36是一种针对组蛋白甲基转移酶SET结构域含蛋白2 (SETD2) 的肽类超级底物，其对应于组蛋白H3赖氨酸36 (H3K36) 的第29至43个氨基酸，且在第31、32、36、37和39位氨基酸上发生了置换。在无细胞检测中，ssK36的甲基化程度比H3K36 (29-43) 高70倍，速度快290倍。
T38711	YF-2 hydrochloride
	YF-2 hydrochloride is a potent histone acetyltransferase activator that exhibits high selectivity and can pass through the blood-brain barrier. It specifically acetylates H3 in the hippocampus, with EC50 values of 2.75 μM, 29.04 μM, and 49.31 μM for CBP, PCAF, and GCN5, respectively. Notably, it does not affect HDAC activity. Moreover, YF-2 hydrochloride demonstrates promising anti-cancer and anti-Alzheimer's disease properties.
T60359	cis-4-Br-2,5-F2-PCPA
	cis-4-Br-2,5-F2-PCPA (S1024) 抑制 LSD1 和 LSD2，Ki 值分别为 94 nM 和 8.4 μM。癌症干细胞中 LSD1异常表达，cis-4-Br-2,5-F2-PCPA 能够通过增加 CCRF-CEM 细胞中二甲基化组蛋白 H3 的 K4 (H3K4) 水平，抑制 LSD1活性和癌细胞增殖。
T68458	Fostriecin (free base)
	Fostriecin (free base) is an inhibitor of the serine/threonine protein phosphatases 2A (PP2A) and 4 (PP4) (IC50s = 3.2 and 3 nM, respectively). It less effectively inhibits topoisomerase II and PP1 (IC50s = 40 and 131 μM, respectively) and does not inhibit PP2B. Through its effects on protein phosphatases, fostriecin increases the level of histone H3 phosphorylation and may alter epigenetic regulation of cell proliferation. On a related note, fostriecin was first identified as an antitumor antib...
T61433	HDAC1-IN-5
	HDAC1-IN-5, a potent inhibitor of HDAC1 with an IC50 value of 15 nM, also exhibits inhibitory activity towards HDAC6 with an IC50 value of 20 nM. In cancer cells, HDAC1-IN-5 enhances the acetylation of both histone H3 and α-tubulin, leading to the activation of caspase 3 and induction of apoptosis. Additionally, HDAC1-IN-5 binds with DNA, causing chromatin damage. Furthermore, it demonstrated strong inhibitory activity against tumor growth in xenograft mice. [1]
T35567	BIX01294 (hydrochloride hydrate)
	The methylation of lysine residues on histones plays a central role in determining euchromatin structure and gene expression. The histone methyltransferase (HMTase) G9a can mono- or dimethylate lysine 9 on histone 3 (H3), contributing to early embryogenesis, genomic imprinting, and lymphocyte development. BIX01294 (hydrochloride hydrate) is a selective inhibitor of G9a HMTase (IC50 = 1.7 μM). It less effectively inhibits the HMTase G9a-like protein (GLP; IC50 = 38 μM) and has no effect on other ...
T73225	OTS193320
	OTS193320 是一种咪唑并 [1,2-a] 吡啶化合物，一种 SUV39H2甲基转移酶活性抑制剂。OTS193320 降低乳腺癌细胞中的全局组蛋白 H3 赖氨酸 9 三甲基化水平并引发凋亡细胞死亡。与单一药剂 OTS193320 或 DOX 相比，OTS193320 与 Doxorubicin(DOX) 的组合可以导致 γ-H2AX 水平以及癌细胞活力的降低。
T35762	MC1742
	MC1742 is an inhibitor of class I histone deacetylases (HDACs; IC50s = 0.1, 0.11, 0.02, and 0.61 μM for HDAC1, -2, -3, and -8, respectively) and class IIb HDACs (IC50s = 7 and 40 nM for HDAC6 and HDAC10, respectively).1 It is selective for class I and class IIb over class IIa HDACs (IC50s = >50 μM for HDAC4, -5, -7, and -9). MC1742 reduces proliferation of HOS, MG-63, RD, A204, SK-ES-1, and A673 sarcoma cancer stem cells (CSCs). It increases levels of acetylated histone H3 and acetylated tubulin...
T36627	Lysine-specific Demethylase Inhibitor (1C) (hydrochloride)
	Lysine-specific demethylase inhibitor (1C) (LSD inhibitor (1C)) is an inhibitor of LSD1, a repressive demethylase selective for histone H3 lysine 4 (H3K4).1,2LSD inhibitor (1C) inhibits LSD1 activity by 85.9% when used at a concentration of 10 μM.1It increases the level of H3K4 methylation, including H3K4me1 and H3K4me2 but not H3K9me2 levels, in HCT116 human colon carcinoma cells.2LSD inhibitor (1C) also induces re-expression of the Wnt signaling pathway proteins secreted frizzle-related protei...
T70588	Tazemetostat HCl
	Tazemetostat HCl is a potent, selective, and orally bioavailable small-molecule inhibitor of EZH2 enzymatic activity. EPZ-6438 induces apoptosis and differentiation specifically in SMARCB1-deleted MRT cells. Treatment of xenograft-bearing mice with EPZ-6438 leads to dose-dependent regression of MRTs with correlative diminution of intratumoral trimethylation levels of lysine 27 on histone H3, and prevention of tumor regrowth after dosing cessation. These data demonstrate the dependency of SMARCB1...
T69937	INCB059872 tosylate
	INCB059872, also known as INCB59872, is a potent, selective, and orally active lysine-specific demethylase 1 inhibitor. INCB059872 binds to and inhibits LSD1, a demethylase that suppresses the expression of target genes by converting the di- and mono-methylated forms of lysine at position 4 of histone H3 (H3K4) to mono- and unmethylated H3K4, respectively, through amine oxidation. LSD1 inhibition enhances H3K4 methylation and increases the expression of tumor-suppressor genes. In addition, LSD...
T63074	Ivaltinostat formic
	Ivaltinostat (CG-200745) formic 是一种口服具有活力的泛 HDAC 抑制剂，具有异羟肟酸部分，能够在催化袋底部结合锌。Ivaltinostat formic 对组蛋白 H3 和微管蛋白的脱乙酰作用具有抑制效果。Ivaltinostat formic 能够促使 p53 的积累，诱导 p53 依赖性反式激活，并提高 MDM2 和 p21 (Waf1/Cip1) 蛋白的表达。Ivaltinostat formic 增加 Gemcitabine 耐药细胞对 Gemcitabine 和 5-Fluorouracil (5-FU) 的敏感性。Ivaltinostat formic 诱导凋亡，并具有抗肿瘤效果。
T36104	Citrulline-specific Probe-Rhodamine
	Protein arginine deiminases (PADs) catalyze the posttranslational modification of arginine residues on proteins to form citrulline, which plays a large role in regulating gene expression. Abnormally high PAD activity has been observed in a host of human diseases. Citrulline-specific probe-rhodamine is a highly sensitive, rhodamine phenylglyoxal-based fluorophore that specifically detects protein citrullination via a chemoselective reaction between glyoxal and citrulline. This chemical probe (com...
T83867	UNC8153 TFA
	UNC8153 是一种 NSD2（组蛋白-赖氨酸 N-甲基转移酶）的降解剂，其通过诱导NSD2的降解，具有350 nM的50%降解常数（DC50）值，并且在20 µM浓度下对NSD2具有选择性，而不选择NSD1和NSD3。在MM.1S多发性骨髓瘤细胞中，UNC8153 (10 µM) 能够诱导NSD2降解并减少组蛋白H3赖氨酸36位二甲基化（H3K36me2），这一效应可以被泛素激活酶抑制剂MLN4924所抑制。它减少了表达带有在1099位上谷氨酸到赖氨酸激活突变的NSD2（NSD2E1099K）的MM.1S细胞的增殖，但在20 µM浓度下，对表达野生型NSD2的MDA-MB-231、U2OS或HEK293细胞无效。UNC8153 (20 µM) 降低了在迁移实验中MM.1S细胞的附着能力。
T70962	MHY219
	MHY219 is a novel HDAC inhibitor. MHY219 induces apoptosis via up-regulation of androgen receptor expression in human prostate cancer cells. MHY219 was shown to enhance the cytotoxicity on DU145 cells (IC50, 0.36 μM) when compared with LNCaP (IC50, 0.97 μM) and PC3 cells (IC50, 5.12 μM). MHY219 showed a potent inhibition of total HDAC activity when compared with SAHA. MHY219 increased histone H3 hyperacetylation and reduced the expression of class I HDACs (1, 2 and 3) in prostate cancer cells. M...

化合物

Histone H3 (1-35) acetate

Cat.No: T38766L

Target: Others

Histone H3 (1-35)

Cat.No: T38766

Synonym: Histone H3 (1-35)

Histone H3 (21-44)

Cat.No: T38785

Synonym: Histone H3 (21-44)

Histone H3 (1-21)

Cat.No: T40993

Synonym: Histone H3 (1-21)

Histone H3 (23-34)

Cat.No: T39580

Synonym: Histone H3 (23-34)

Histone H3 (5-23)

Cat.No: T40407

Synonym: Histone H3 (5-23)

Histone H3 (1-25), amide

Cat.No: T38784

Synonym: Histone H3 (1-25), amide

Histone H3 (116-136), C116-136

Cat.No: T41061

Synonym: Histone H3 (116-136), C116-136

Histone H3 (21-44)-GK-biotin (trifluoroacetate salt)

Cat.No: T36576

Synonym: Histone H3 (21-44)-GK-biotin (trifluoroacetate salt)

Histone H3 (21-44)-GK-biotin amide (trifluoroacetate salt)

Cat.No: T36979

Synonym: Histone H3 (21-44)-GK-biotin amide (trifluoroacetate salt)

Cat.No: T6421

Target: HDAC

Cat.No: TQ0059

Synonym: ABT-348

Target: VEGFR, FLT, c-RET, PDGFR, Aurora Kinase

Histone H3 Antibody #9715R

Cat.No: T64592

Cat.No: T0029

Synonym: Duracaine,Spinocaine,普鲁卡因,Novocaine,Vitamin H3,奴夫卡因

Target: Histone Demethylase, DNA/RNA Synthesis, Sodium Channel

Acetyl-Histone H3 (Lys9) (C5B11) Rabbit mAb #9649R

Cat.No: T64611

Cat.No: T27083

Target: Epigenetic Reader Domain, Histone Acetyltransferase, HDAC

Cat.No: T5468

Target: Others, Epigenetic Reader Domain, Histone Acetyltransferase

Cat.No: T8344

Target: Apoptosis, Histone Acetyltransferase

Cat.No: T28996

Synonym: TP 064

Target: Histone Methyltransferase

Cat.No: T64529

Synonym: MDL 800,MDL800

Target: Sirtuin

Cat.No: T14936

Synonym: CG-200745

Target: HDAC

Cat.No: T29014

Butyrolactone 3

Cat.No: T14839

Target: Others

Cat.No: T38774

Synonym: E67-2

Histone H3K27Me1 (23-34) (trifluoroacetate salt)

Cat.No: T36980

Synonym: Histone H3K27Me1 (23-34) (trifluoroacetate salt)

Cat.No: T11880

Target: Histone Demethylase

Cat.No: T11881

Target: Histone Demethylase

Cat.No: T39073

Cat.No: T81831

Target: Sirtuin

Photoswitchable PAD Inhibitor (technical grade)

Cat.No: T35817

Cat.No: T82313

Target: HDAC

Cat.No: T83755

YF-2 hydrochloride

Cat.No: T38711

cis-4-Br-2,5-F2-PCPA

Cat.No: T60359

Fostriecin (free base)

Cat.No: T68458

Cat.No: T61433

BIX01294 (hydrochloride hydrate)

Cat.No: T35567

Cat.No: T73225

Cat.No: T35762

Lysine-specific Demethylase Inhibitor (1C) (hydrochloride)

Cat.No: T36627

Tazemetostat HCl

Cat.No: T70588

INCB059872 tosylate

Cat.No: T69937

Ivaltinostat formic

Cat.No: T63074

Citrulline-specific Probe-Rhodamine

Cat.No: T36104

Cat.No: T83867

Cat.No: T70962

Cat. No.	Product Name	Target	Signaling Pathways
T64353	4-tert-Octylphenol	Endogenous Metabolite	Metabolism
	4-tert-Octylphenol 是一种干扰内分泌的化学物质及雌激素药物，能诱导子代小鼠脑神经元祖细胞的凋亡，并通过减少溴脱氧尿苷（BrdU）、有丝分裂标志物Ki67以及磷酸组蛋白H3（p-Histone-H3）的表达，导致神经元祖细胞的增殖减少。这种物质不仅会干扰小鼠的大脑发育，还会影响其行为。

天然产物

4-tert-Octylphenol

Cat.No: T64353

Target: Endogenous Metabolite

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